Institut des Sciences Moléculaires d'Orsay



lundi 22 juillet

Mise à jour
mercredi 17 juillet

Accueil > Séminaires > Année 2019 > Séminaire de Brendan Michael McLaughlin (29 avril)

Séminaire de Brendan Michael McLaughlin (29 avril)

Centre for Theoretical Atomic Molecular and Optical Physics (CTAMOP) School of Mathematics and Physics, Queens University Belfast

par Martrenchard-Barra Séverine - 24 avril 2019

Quantum Chemistry and its role in dynamical studies in ultra-cold collisions

The structure and properties of molecules and their cations plays a fundamental role in a range of dynamical studies such as ; ultra-cold collisions [1-3], laser cooling and trapping, dissociative electron attachment, dissociative recombination, electron scattering, photoionization [4] and ultrafast dynamics. Ultra-cold hybrid ion-atom traps offer the possibility of microscopic manipulation of quantum coherence in the gas using the ion as a probe. The inelastic processes, particularly charge transfer, may play a significant role in the process of ion loss and is of current interest experimentally. The study of ultra-cold molecules tightly trapped in an optical lattice can expand the frontier of precision measurements and spectroscopy and lead to a deeper insight into molecular and fundamental physics. The interpretation of experimental results requires detailed information on the structure, properties and dynamics and is a prime example where quantum chemistry plays a fundamental role. Electron-density distributions, transition dipole moments and potential-energy surfaces are important for predicting the physical properties and chemical reactivity of molecular systems. Methods used to obtain the structure and dynamics of molecular systems for a variety of molecular complexes will be outlined. The fundamental role played by quantum chemistry in these investigations will be discussed for cross sections and rate coefficients evaluation, for radiative loss, association and charge transfer for a variety of diatomic complexes ; NaCa+, HeC+. CH+, CH, SiO, CS and C2 [5-11]. The NaCa+ cation is of current interest to the efforts (experimental and theoretical) of the University of Connecticut group [12,13].

[1] H. D. L. Lamb et al., Phys. Rev A 86, 022719 (2012)
[2] B. M. McLaughlin et. al., J. Phys. B : At. Mol. Opt. Phys. 47, 145201 (2014)
[3] P. C. Stancil et al., Bull. Am. Phys. Soc. 59, 46 (2014)
[4] G. Shen et al., J. Phys. B : At. Mol. Phys. 48, 105203 (2015)
[5] J. F. Babb and B. M. McLaughlin, J. Phys. B : At. Mol. Opt. Phys. 50, 044003 (2017)
[6] J. F. Babb and B. M. McLaughlin, MNRAS 468, 2052 (2017)
[7] J. F. Babb, H. Merryman and B. M. McLaughlin, Astrophys.J., submitted (2019).
[8] J. F. Babb, R. T. Smyth and B. M. McLaughlin, Astrophys. J., in press (2019),
[9] M. Cairnie et al., MNRAS 471, 2481 (2017)
[10] R. Pattillo et al., Astrophys. J, 858, 10 (2018)
[11] R. C. Forrey et al., MNRAS 479, 4727 (2018)
[12] J. Kwolek et al., Bull. Am. Phys. Soc. V09, 00002 (2019)
[13] M. Gacesa et al., Phys. Rev. A 94, 013407 (2016)

Séminaire de Brendan Michael McLaughlin - 106.5 kio

29 avril 2019