Associate Professor at Université Paris-Saclay
Holder of the French Habilitation (HDR)
Contact:
Education and Scientific Experience
1998 – 2001: Magistère de l’Ecole Normale Supérieure (chemistry)
2000 – 2003: PhD in Inorganic Chemistry (University Paris 6)
PhD advisor: Anna Proust
Performed at Inorganic Chemistry and Molecular Materials Laboratory, University Paris 6
2003 – 2004: Postdoctorate at Surface OrganoMetallic Chemistry Laboratory in Lyon
Supervisor: Jean-Marie Basset
2004 – 2005: Postdoctorate at Coordination Chemistry Laboratory in Toulouse
Supervisor: Michel Etienne
2005 – 2006: ATER at Interfaces, Treatment and DYnamic of Systems Laboratory in Paris 7
Supevisor: Guillaume Viau
Since September 2006 : Associate Professor at Université Paris-Saclay
2013: French Habilitation Thesis (HDR), (Université Paris Sud XI)
Nanoparticules and surfaces: functionalization and preparation of organic – inorganic hybride structures
Président of the habilitation committee: Marie-Geneviève Barthès-Labrousse
Referees: Pedro de Oliveira, Pierre Mialane, Souad Ammar
Examinators: François Rochet, Claire-Marie Pradier, Anne Lafosse
Research activities
My current research concerns, in the context of molecular electronics, the synthesis of nano-objects (nanoparticles, metal-oxo clusters called polyoxometalates or heteropolyanions) and their deposition on various supports such as Self-Assembled Monolayers or SAMs. These self-assembled layers are prepared by the Langmuir-Blodgett technique, by solution chemistry methods or by ultra-high vacuum evaporation of molecules of interest in electronics. Depending on the needs, they can be modified by laser irradiation or by impact of low energy electrons (typically < 50 eV). These molecular films as well as the deposits of nano-objects can be characterized by various spectroscopic techniques such as Sum Frequency Generation (SFG) spectroscopy, infrared, XPS, UPS, NEXAFS and High Resolution Electron Energy Loss Spectroscopy (HREELS). Information on the two-dimensional crystal structure of the Langmuir-Blodgett films is extracted from Grazing Incidence X-ray Diffraction (GIXD) measurements carried out at the SOLEIL synchrotron.
Another part of my research concerns catalysis, in particular through the immobilization of organometallic complexes on surfaces and the synthesis of new species. In the past, I have also worked with ices of interest in astrochemistry.
Supervision
Trainings of two 1st year Ms and three 2nd year Ms students
2003 – 2004: Co-supervision of Amélie Thomas’s PhD (2nd year)
2006 – 2009: Co-supervision of Hicham Hamoudi’s PhD
2012 – 2015: Participation to the supervision of Justine Houplin’s PhD
2015 – 2018: Participation to the supervision of Leo Sala’s PhD
2024 – 2027: Co-direction of Xingtong Li’s PhD
Teaching activities
PCSO lectures: General chemistry 1
L1 BCST lectures: Chemistry 1: from atom to matter
Common core lectures of PeiP1 (1styear of preparation school of Polytech Paris-Saclay Engineering School): Thermochemistry
Scientific course lectures of PeiP1: Solution chemistry
L2 Chemistry lectures: Thermochemistry: spontaneity andequilibrium
L2 Chemistry tutorials:Thermochemistry: spontaneity and equilibrium
L2 Chemistry lectures:Kinetics and Catalysis (Chain reactions section and Catalysis section)
L3 interfaces Physics and Chemistry at the interfaces lectures and tutorials: Notions of chemical kinetics
M1 Chemistry tutorials: Surface functionalization
Administrative activities
In charge ofL3 interfaces Physics and Chemistry at the interfaces of the Orsay UFR of Sciences
In charge of the Chemistry teaching for the PeiP of Polytech Paris-Saclay
Elected member of the Orsay Faculty of Science Council
Member of the Pedagogy Commission
Member of the Engineering, Administrative, Social and Healthcare Commission
Member of the Orsay Teachers’ Committee
In charge of NanoSAM Chemistry Platform of ISMO
Coordinator of the ISMO Energy axis
Previous administrative activities
Elected full member of the CNU 31st section (from 2012 to 2019)
Assessor B (from 2010 to 2014) and then Vice-President B (from 2014 to 2019) of the Chemistry CCSU (31st – 32nd – 33rd sections) of the University
Elected full member of the Chemistry CCSU (from 2020 to 2021)
Member of the Council of the Chemistry Department of the UFR Sciences (from 2010 to 2019)
Co-leader of PeiP of Polytech Paris Sud Engineering School (from 2012 to 2016)
In charge of PeiP2 = 2ndyear of preparation school of Polytech Paris Sud Engineering School (from 2008 to 2016)
Co-leader of the Physical and General Chemistry Working Group for the Bachelor of Chemistry (from 2018 to 2021)
Digital resources for teaching
Oral and poster presentations
2021: Invited oral communication at the WIMS symposium– Amiens – C. Dablemont – « WIMS and experimental sciences at the University »
2022 : Poster presentation at the WIMS symposium –Belfort-Montbéliard from June 13th to 15th – C. Dablemont, S. Lemaire, M.-C. David – « Thermochemistry and chemical kinetics – Improving and creating WIMS resources »
2022 : Poster presentation at the WIMS – Belfort-Montbéliard from June 13th to 15th – E. Porcel, M.-J. Ramage, C. Dablemont – « WIMS for solution chemistry at the University »
2022 : Poster presentation at the Journées Nationales de l’Association des Professeurs de Mathématiques de l’Enseignement Public (APMEP) – C. Dablemont, S. Lemaire, M.-C. David – « Thermochemistry and chemical kinetics – Improving and creating WIMS resources»
2023 : Poster presentation at the Journée Lycée Université of the Université Paris-Saclay – C. Dablemont, S. Lemaire, M.-C. David – « Thermochemistry and chemical kinetics – Improving and creating WIMS resources»
WIMS digital resource production
For chemical kinetics: creation of a 6-exercise module on formal chemical kinetics and of a 12-exercise module on differential equations in chemical kinetics+ improvement of a 5-exercise module on kinetics
For solution chemistry: improvement of a 5-exercise module on precipitation and creation of 3 exercises + improvement of a 3-exercise module on complexation and creation of 1-exercise + creation of 5 exercises in an 18-exercise module on oxidation-reduction + improvement of a 14-exercise module on acid-base reactions
For thermochemistry: improvement of an 11-exercise module on perfect gases + improvement of an 18-exercise module on thermal machines and creation of 6 exercices +improvement of a 13-exercise module on chemical reaction quantities (enthalpy, entropy and free enthalpy) and creation of 16 exercises
For experimental sciences: creation of a WIMS course on significant figures
Publications
2024
A. Ouvrard, N. Alyabyeva, A.-M. Zakaria, K. Yuan, C. Dablemont, R. Lazzari, F. Charra, B. Bourguignon. Change of composition and surface plasmon resonance of Pd/Au core/shell nanoparticles triggered by CO adsorption. Chem. Phys., 161, 124713.
2023
A. Fatima, Y. Smortsova, C. Falaise, N. Leclerc, M. Haouas, E. Cadot, S. Cordier, Y. Molard, T. Pino, C. Dablemont, R. Méallet, K. Steenkeste, M.-H. Ha-Thi. Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2- cluster and polyoxometalates. Chem. Commun., 59, p. 10988-10991
2021
A. Rathore, M. Cipriani, C.-C. Huang, L. Amiaud, C. Dablemont, A. Lafosse, O. Ingólfsson, D. De Simone, S. De Gendt. Electron-induced fragmentation mechanisms in organic monomers and their implications for photoresist optimization for EUV lithography. Phys. Chem. Chem. Phys., 23, p. 9228-9234
2018
N. Kalashnyk, L. Amiaud, C. Dablemont, A. Lafosse, K. Bobrov, L. Guillemot. Strain relaxation and epitaxial relationship of perylene overlayer on Ag(110). Chem. Phys., 148, p. 214702
L. Sala, I. B. Szymańska, C. Dablemont, A. Lafosse, L. Amiaud. Response under low energy irradiation of a thin film of a potential copper precursor for Focused Electron Beam Induced Deposition (FEBID). Beilstein J. Nanotechnol., 9, p. 57-65
2017
D. Houdoux, J. Houplin, L. Amiaud, A. Lafosse, C. Dablemont. Interfacial water on organic substrates at cryogenic temperatures: hydrogen bonding and quantification in the submonolayer regime. Phys. Chem. Chem. Phys., 19, p. 2304-2312
2015
J. Houplin, C. Dablemont, L. Sala, A. Lafosse, L. Amiaud. Electron processing at 50 eV of terphenylthiol Self-Assembled Monolayers: contribution of primary and secondary electrons. Langmuir, 31, p. 13528-13534.
J. Houplin, L. Amiaud, C. Dablemont, A. Lafosse. DOS and electron attachment effects in the electron-induced vibrational excitation of terphenylthiol SAMs. Phys. Chem. Chem. Phys., 17, p. 30721-30728
J. Houplin, L. Amiaud, T. Sedzik, C. Dablemont, D. Teillet-Billy, N. Rougeau, A. Lafosse. A combined DFT/HREELS study of the vibrational modes of terphenylthiol SAMs. Eur. Phys. J. D, 69, p. 217.
2011
L. Pasquali, F. Terzi, R. Seeber, S. Nannarone, D. Datta, C. Dablemont, H. Hamoudi, M. Canepa, V. A. Esaulov. A UPS, XPS and NEXAFS study of self-assembly of standing 1,4-benzenedimethanethiol SAMs on gold. Langmuir, 27, p. 4713-4720
H. Hamoudi, C. Dablemont, V. A. Esaulov. Disorder, solvent effects and substitutional self-assembly of alkane dithiols from alkane thiol SAMs. Surf. Sci., 605, p. 116-120.
2010
H. Hamoudi, M. Prato, C. Dablemont, O. Cavalleri, M. Canepa, V. A. Esaulov. Self-Assembly of 1,4-Benzenedimethanethiol Self-Assembled Monolayers on Gold. Langmuir, 26, p. 7242-7247.
2009
L. N. Serkovi Loli, H. Hamoudi, J. E. Gayone, M. L. Martiarena, E. A. Sanchez, O. Grizzi, L. Pasquali, S. Nannarone, B. P. Doyle, C. Dablemont, V. A. Esaulov. Growth of N,N’-Bis(1-ethylpropyl)perylene-3,4,9,10-tetracarboxdiimide Films on Ag(111). Phys. Chem. C, 113, p. 17866-17875
M. A. Daza Millone, H. Hamoudi, L. Rodríguez, A. Rubert, G. A. Benitez, M. E. Vela, R. C. Salvarezza, J. E. Gayone, E. A. Sanchez, O. Grizzi, C. Dablemont, V. A. Esaulov. Self-Assembly of Alkanedithiols on Au(111) from Solution: Effect of Chain Length and Self-Assembly Conditions. Langmuir, 25, p. 12945-12953.
2008
C. Dablemont, P. Lang, C. Mangeney, J.-Y. Piquemal, V. Petkov, F. Herbst, G. Viau. FTIR and XPS Study of Pt Nanoparticle Functionalisation and Interaction with Alumina. Langmuir, 24, p. 5832-5841
H. Hamoudi, C. Dablemont, V. A. Esaulov. Interaction of Li+ with a Au(100) surface. Surf. Sci., 602, p. 2486-2490
H. Hamoudi, Z. Guo, M. Prato, C. Dablemont, W. Q. Zheng, B. Bourguignon, M. Canepa, V. A. Esaulov. On the self assembly of short chain alkanedithiols. Phys. Chem. Chem. Phys., 45, p. 6836-6841
Z. Guo, W. Zheng, H. Hamoudi, C. Dablemont, V. A. Esaulov, B. Bourguignon. On the chain length dependence of CH3 vibrational mode relative intensities in sum frequency generation spectra of self assembled alkanethiols. Surf. Sci., 602, p. 3551-3559
2007
N. Lidgi-Guigui, C. Dablemont, D. Veautier, G. Viau, P. Seneor, F. Nguyen Van Dau, C. Mangeney, A. Vaurès, C. Deranlot, A. Friederich. Grafted 2D Assembly of Colloidal Metal Nanoparticles for Application as a Variable Capacitor. Adv. Mater., 19, p. 1729-1733.
G. Tosin, C. C. Santini, A. Baudouin, A. De Mallman, S. Fiddy, C. Dablemont, J. M. Basset. Reactivity of Silica-Supported Hafnium Tris-neopentyl with Dihydrogen: Formation and Characterization of Silica Surface Hafnium Hydrides and Alkyl Hydride. Organometallics, 26, p. 4118-4127
N. Bedford, C. Dablemont, G. Viau, P. Chupas, V. Petkov. 3-D structure of nanosized catalysts by high-energy X-ray diffraction and reverse Monte Carlo simulations: Study of Ru. Phys. Chem. C, 111, p. 18214-18219.
2006
S. Soignier, M. Taoufik, E. Le Roux, G. Saggio, C. Dablemont, A. Baudouin, F. Lefebvre, A. de Mallmann, J. Thivolle-Cazat, J.-M. Basset, G. Sunley, B. M. Maunders. Tantalum hydrides supported on MCM-41 mesoporous silica: activation of methane and thermal evolution of the tantalum-methyl species. Organometallics, 25, p. 1569-1577.
P. Oulié, J. Teichert, L. Vendier, C. Dablemont, M. Etienne. Aromatic interactions in hydrotris(indazolyl)borate organometallic complexes: control of an alkyne ligand orientation in the crystal. New J. Chem., 30, p. 679-682
B. Rhers, C. Lucas, M. Taoufik, E. Herdtweck, C. Dablemont, J.-M. Basset, F. Lefebvre. Synthèse et caractérisation de nouveaux complexes aryloxy à base de tungstène. C. R. Chimie, 9, p. 1169-1177
F. Bini, C. Rosier, R. Petroff Saint-Arroman, E. Neumann, C. Dablemont, A. de Mallmann, F. Lefebvre, G. P. Niccolai, J.-M. Basset, M. Crocker, J.-K. Buijink. Surface Organometallic Chemistry of Titanium: Synthesis, Charaterization, and Reactivity of (≡Si-O)nTi(CH2C(CH3)3)4-3 (n = 1,2) Grafted on Aerosil Silica and MCM-41. Organometallics, 25, p. 3743-3760
C. Dablemont, C. G. Hamaker, R. Thouvenot, Z. Sojka, M. Che, E. A. Maatta, A. Proust. Functionalization of Heteropolyanions – Osmium and Rhenium Nitrido Derivatives of Keggin- and Dawson-Type Polyoxotungstates: Synthesis, Characterization and Multinuclear (183W, 15N) NMR, EPR, IR and UV/Vis Fingerprints. Chem. Eur. J., 12, p. 9150-9160. Cover picture.
2005
C. Dablemont, A. Proust, R. Thouvenot, C. Afonso, F. Fournier, J.-C. Tabet. Functionalization of polyoxometalates: from Lindqvist to Keggin derivatives. 2. Investigation of the reactivity of arylamines, organo-hydrazines and tolylisocyanate towards PW12-xMxO40n- Keggin anions. Dalton Trans., 10, p. 1831-1841
A. Thomas, C. Dablemont, J.-M. Basset, F. Lefebvre. Comparison of H3PW12O40 and H4SiW12O40 heteropolyacids supported on silica by 1H MAS NMR. C. R. Chimie, 8, p. 1969-1974
2004
C. Dablemont, A. Proust, R. Thouvenot, C. Afonso, F. Fournier, J.-C. Tabet. Functionalization of polyoxometalates: from Lindqvist to Keggin derivatives: 1. Synthesis, solution studies and spectroscopic and ESI mass spectroscopy characterization of the rhenium phenyl-imido tungstophosphate PW11O39Re(NC6H5)4-. Inorg. Chem., 43, p. 3514-3520
2003
C. Dablemont, A. Proust, P. Gouzerh, C. Afonso, F. Fournier, J.-C. Tabet. Characterization of Keggin’s type polyoxometalates with multiple metal-nitrogen bonds by ion-trap mass spectrometry. Proc. Am. Soc. Mass Spectrom.
2002
H. Kwen, S. Tomlinson, E. A. Maatta, C. Dablemont, R. Thouvenot, A. Proust, P. Gouzerh. Functionalized heteropolyanions: high-valent metal nitride fragments incorporated into a Keggin polyoxometalate structure. Chem. Commun., p. 2970-2971.